HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → HCID 86665165, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Reactant | HCID 66640067 | HCID 66640067 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 86665165 | HCID 86665165 | — |
Reaction Steps
140 μl (1.8 mMol) DMF are added to an ice-cooled solution of 3.6 ml (43 mMol) oxalylchloride in 150 CH2Cl2. Then a suspension of 8.8 g (36 mMol) 6-carboxymethyl-naphthalene-1-carboxylic acid methyl ester in 400 ml CH2Cl2 is added during 1 h. After 1.5 h stirring in the ice-bath, the reaction mixture is concentrated in vacuo, yielding the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08133886B2 |
| Source dataset | uspto-grants-2012_03 |
| ORD ID | ord-f686fb38dfdd4939925725bd958003e0 |
| Source note | uspto-grants-2012_03 |