HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 58942851, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Sodium triacetoxyborohydride | HCID 5049666 | — |
| Reactant | Methyl 2-(3-formylphenyl)acetate | HCID 11819590 | — |
| Reactant | HCID 66782075 | HCID 66782075 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | HCID 58942851 | HCID 58942851 | — |
Reaction Steps
The product from step (ii) (3.1 g) and methyl(3-formylphenyl)acetate (1.6 g) were dissolved in NMP (30 ml) and stirred for 15 min. Sodium triacetoxyborohydride (3.7 g) was added and the mixture stirred at rt for 20 h. After addition of methanol (1 ml), the mixture was purified by SCX, which afforded the subtitle compound. Yield 3.1 g.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08138172B2 |
| Source dataset | uspto-grants-2012_03 |
| ORD ID | ord-9584ee65c5bc4535ac8415fcc064e815 |
| Source note | uspto-grants-2012_03 |