Water → 2-Ethylhexanol

HRID 1096468Notes

Reaction equation

HRID 1096468 reaction equation
O.O1[CH:8]2[CH:3]1[CH2:4][CH:5]1[C:12](=O)N(CC=C)[C:9](=[O:10])[CH:6]1[CH2:7]2>C1(C)C=CC=CC=1>[CH2:5]([CH:6]([CH2:7][CH2:8][CH2:3][CH3:4])[CH2:9][OH:10])[CH3:12]

Participants

4

Reactant 2

HCID 962WaterHCID 252422084,5-epoxy-N-allylcyclohexane-1,2-dicarboximide

Product 1

HCID 77202-EthylhexanolYield 0.3%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

In a 300 ml four-necked flask equipped with a reflux condenser, Dean-Stark water separator, thermometer, stirrer, dropping funnel and oil bath there were charged 22.8 g of the 4,5-epoxy-N-allylcyclohexane-1,2-dicarboximide obtained in Reference Example 2, 180 g of toluene and 0.05 g of a 2-ethylhexanol solution containing 2 wt % platinic chloride, after which the oil bath kept at 140° C. was used for azeotropic dewatering while circulating for 1 hour, and after confirming lack of water runoff, a total of 36.3 g of the silicon compound represented by the following formula (X):

Workup

  1. customIn a 300 ml four-necked flask equipped with a reflux condenser
  2. customthermometer, stirrer, dropping

Sources & evidence

ORD record
ord-2e974d67e3404084ad671872a6aee317
Source dataset
uspto-grants-2012_03
Patent number
US08138296B2

Reaction notes

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