1,2-Dichlorobenzene → 1,2-Didodecylbenzene
Reaction equation
[CH2:1]([Mg]Br)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].Cl[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=1Cl>>[CH2:1]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=1[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]Participants
3
Procedure
1,2-Didodecylbenzene was synthesized with reference to the method described in “Synthesis”, 1993, pp. 387-390 from 1,2-dichlorobenzene and n-dodecylmagnesium bromide as follows.
Workup
- customdescribed in “Synthesis”, 1993
Sources & evidence
- ORD record
- ord-208a599440144040a13d02a787ae9229
- Source dataset
- uspto-grants-2012_03
- Patent number
- US08138355B2
Reaction notes
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