HRID1105534

反应详情

EQUATION

反应方程式

HRID 1105534 的结构方程式

AUXILIARIES

试剂、催化剂与溶剂

1

CONDITIONS

反应条件

温度
105 °C

PROCEDURE

实验过程

Proceeding as in Example 1, into a 100 cc flask were placed to react: 4.1 g of potassium 3-butenoate (3.3 10-2 mols), 6 g of styryl bromide, a cis-trans mixture, (3.3 10-2 mols), 2.9 g of Ni(PPh3)3 (3.3 10-2 mols) and 40 cc of ethyl alcohol. The mass was heated up to 105° C. under nitrogen atmosphere, for about 2 hours. Operating as in Example 1, there were obtained 2.2 g of 6-phenyl-3,5-hexadienoic acid, a mixture of isomers containing double cis and trans bonds.

WORKUP

后处理

  1. customProceeding as in Example 1, into a 100 cc flask were placed
  2. customto react