HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,11-Dibromoundecane → Pentadecane, 1-bromo-14-methyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,11-Dibromoundecane | HCID 85551 | — |
| Reactant | HCID 178418529 | HCID 178418529 | — |
| Catalyst | Lithium copper chloride | HCID 86737138 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | Pentadecane, 1-bromo-14-methyl- | HCID 10881292 | — |
Reaction Conditions
| Temperature | -10 °C |
|---|
Reaction Steps
By a procedure analogous to that described above, 3-methylbutyl magnesium bromide in tetrahydrofuran is reacted with 34.5 g. (0.11 moles) of 1,11-dibromoundecane and 0.2 g. of lithium copper chloride in 75 ml. of tetrahydrofuran. After 1 hour stirring at -10° C., the solution is evaporated, and the resultant oil is distilled in vacuo to yield the colorless 1-bromo-14-methylpentadecane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04309553 |
| Source dataset | uspto-grants-1982_01 |
| ORD ID | ord-938313edfceb40c0a40f81f7cf67e653 |
| Source note | uspto-grants-1982_01 |