HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,6-Dichlorobenzoic acid → HCID 12832597, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,6-Dichlorobenzoic acid | HCID 5758 | — |
| Reactant | Chloroacetonitrile | HCID 7856 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 18-Crown-6 | HCID 28557 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 12832597 | HCID 12832597 | 61% |
Reaction Steps
This compound was prepared in the manner of Example 1, using 10.0 grams (0.052 mole) of 2,6-dichlorobenzoic acid, 2.9 grams (0.052 mole) of potassium hydroxide, 3.9 grams (0.052 mole) of chloroacetonitrile, and 1.4 grams of 1,4,7,10,13,16-hexaoxacyclooctadecane in 160 ml of dry toluene. The crude product was distilled to give 7.3 grams of cyanomethyl 2,6-dichlorobenzoate; bp 107°/0.006 mm. The ir and the nmr spectra were consistent with the proposed structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04309566 |
| Source dataset | uspto-grants-1982_01 |
| ORD ID | ord-c0d4e63401ce422d8c4f176f9760f01d |
| Source note | uspto-grants-1982_01 |