HuagongsheHuagongshe Chemistry Print Report · For research reference only
Metaperiodic acid → (+-)-6-Methoxy-2,6-dimethylheptanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Metaperiodic acid | HCID 65185 | — |
| Reactant | 1,2-Octanediol, 7-methoxy-3,7-dimethyl- | HCID 112490 | — |
| Reactant | Sodium Bicarbonate | HCID 516892 | — |
| Solvent | Water | HCID 962 | — |
| Product | (+-)-6-Methoxy-2,6-dimethylheptanal | HCID 112491 | 29.7% |
Reaction Steps
7-Methoxy-3,7-dimethyl octan-1,2-diol (40 g) was treated with periodic acid in tetrahydrofuren; work up with water followed by diluted sodium bicarbonate wash gave the aldehyde (10 g) with specific rotating α(22/D+13.69.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04311617 |
| Source dataset | uspto-grants-1982_01 |
| ORD ID | ord-532a102e96824f5697efc2a90829ec12 |
| Source note | uspto-grants-1982_01 |