Tin atom → Technetium

HRID 1106016Notes

Reaction equation

HRID 1106016 reaction equation
[CH:1]1[C:6]([C:7]([C:18]2[CH:23]=[CH:22][C:21]([OH:24])=[C:20]([C:25]([OH:27])=[O:26])[CH:19]=2)=[C:8]2[CH:14]=[C:13]([C:15]([OH:17])=[O:16])[C:11](=[O:12])[CH:10]=[CH:9]2)=[CH:5][C:4]([C:28]([OH:30])=[O:29])=[C:3]([OH:31])[CH:2]=1.[NH3:32].N.N.[Sn].[Tc:36]([O-])(=O)(=O)=O>>[Tc:36].[CH:9]1[C:8]([C:7]([C:6]2[CH:1]=[CH:2][C:3]([OH:31])=[C:4]([C:28]([OH:30])=[O:29])[CH:5]=2)=[C:18]2[CH:19]=[C:20]([C:25]([OH:27])=[O:26])[C:21](=[O:24])[CH:22]=[CH:23]2)=[CH:14][C:13]([C:15]([OH:17])=[O:16])=[C:11]([OH:12])[CH:10]=1.[NH3:32].[NH3:32].[NH3:32]

Participants

5

Reactant 3

HCID 5352426Tin atomHCID 9543089Pertechnate2×HCID 13710524569-58-4

Product 2

HCID 23957TechnetiumHCID 13710524569-58-4

Procedure

To a vessel containing 2 mg. of aluminon and a piece of tin foil was added 1 ml. of pertechnetate solution and the pH adjusted to 5 with acid. The liquid mixture was allowed to stand for 15 minutes. Essentially all the pertechnetate was reduced to give a complex of technetium with the aluminon.

Workup

  1. additionTo a vessel containing 2 mg

Sources & evidence

ORD record
ord-a779b8b65a5f41b6b4d109474a00e309
Source dataset
uspto-grants-1982_01
Patent number
US04311689

Reaction notes

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