HCID 53739006, compound → HCID 20554453, compound

HRID 1106044Notes

Reaction equation

HRID 1106044 reaction equation
C([O:8][C:9](=[O:23])[CH:10]([CH3:22])[CH2:11][CH:12]([C:17]([O:19][CH2:20][CH3:21])=[O:18])[CH2:13][CH2:14][CH2:15][CH3:16])C1C=CC=CC=1>C(O)C.[Pd]>[CH2:20]([O:19][C:17]([CH:12]([CH2:13][CH2:14][CH2:15][CH3:16])[CH2:11][CH:10]([CH3:22])[C:9]([OH:23])=[O:8])=[O:18])[CH3:21]

Participants

4

Reactant 1

HCID 53739006HCID 53739006, compound

Product 1

HCID 20554453HCID 20554453, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

4-ethoxycarbonyl-2-methyloctanoic acid benzyl ester (10 g) is dissolved in ethanol (100 ml), 10% palladium on charcoal (2 g) is added, and the mixture is hydrogenated until complete removal of the benzyl ester is achieved to yield 4-ethoxycarbonyl-2-methyloctanoic acid.

Workup

  1. customthe mixture is hydrogenated until complete removal of the benzyl ester

Sources & evidence

ORD record
ord-72469a1dc1fa49feadb41f17d7bbba84
Source dataset
uspto-grants-1982_01
Patent number
US04311705

Reaction notes

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