Iodine → HCID 56977465, compound

HRID 1106087Notes

Reaction equation

[SH:1][CH2:2][CH:3]([CH3:18])[C:4]([N:6]1[CH2:13][C:12]([O:16][CH3:17])([O:14][CH3:15])[CH2:11][C@H:7]1[C:8]([OH:10])=[O:9])=[O:5].II>>[CH3:18][C@H:3]([CH2:2][S:1][S:1][CH2:2][C@@H:3]([CH3:18])[C:4]([N:6]1[CH2:13][C:12]([O:16][CH3:17])([O:14][CH3:15])[CH2:11][C@H:7]1[C:8]([OH:10])=[O:9])=[O:5])[C:4]([N:6]1[CH2:13][C:12]([O:16][CH3:17])([O:14][CH3:15])[CH2:11][C@H:7]1[C:8]([OH:10])=[O:9])=[O:5]

Participants

Reactant 2

HCID 807Iodine

HCID 12821147HCID 12821147, compound

Product 1

HCID 56977465HCID 56977465, compound

Procedure

(S)-1-(3-Mercapto-2-methyl-1-oxopropyl)-4,4-dimethoxy-L-proline from Example 4 is reacted with iodine according to the procedure of Example 125 to yield (S,S,S,S)-1,1'-[dithiobis(2-methyl-1-oxo-3,1-propanediyl)]bis[4,4-dimethoxy-L-proline].

Sources & evidence

ORD record: ord-89149a88a4884da78157d1a9a7c5d404
Source dataset: uspto-grants-1982_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04311697

Reaction notes

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