Acetic Anhydride → HCID 19101883, compound

HRID 1106127Notes

Reaction equation

HRID 1106127 reaction equation
[CH:1]([O:3][CH:4]1[CH2:9][C:8]([CH3:11])([CH3:10])[NH:7][C:6]([CH3:13])([CH3:12])[CH2:5]1)=[CH2:2].[C:14](OC(=O)C)(=[O:16])[CH3:15]>N1C=CC=CC=1>[CH:1]([O:3][CH:4]1[CH2:5][C:6]([CH3:13])([CH3:12])[N:7]([C:14](=[O:16])[CH3:15])[C:8]([CH3:11])([CH3:10])[CH2:9]1)=[CH2:2]

Participants

4

Reactant 2

HCID 7918Acetic AnhydrideHCID 19101879HCID 19101879, compound

Product 1

HCID 19101883HCID 19101883, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

40 g of 2,2,6,6-tetramethyl-4-piperidyl vinyl ether were dissolved in 270 ml of dry pyridine and 200 ml of acetic anhydride were added. The mixture was warmed slowly and finally was refluxed for 36 hours. The volatile constituents were evaporated off under a water pump vacuum on a boiling water bath and the residue was distilled under a high vacuum. Boiling point 88°/0.1 mm Hg.

Workup

  1. temperatureThe mixture was warmed slowly
  2. temperaturefinally was refluxed for 36 hours
  3. customThe volatile constituents were evaporated off under a water pump vacuum on a boiling water bath
  4. distillationthe residue was distilled under a high vacuum

Sources & evidence

ORD record
ord-cf50ad627ec14c2dafb2efde2c6d4bae
Source dataset
uspto-grants-1982_01
Patent number
US04311820

Reaction notes

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