Citric Acid → HCID 86738219, compound

HRID 1106203Notes

Reaction equation

HRID 1106203 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[C:3]([CH3:7])[CH:2]=1.Br[CH2:9][CH:10]=[C:11]([CH3:13])[CH3:12].[OH-].[C:15]([OH:27])(=[O:26])[CH2:16][C:17]([CH2:22][C:23]([OH:25])=[O:24])([C:19]([OH:21])=[O:20])[OH:18]>C(#N)C>[C:15]([O-:27])(=[O:26])[CH2:16][C:17]([CH2:22][C:23]([O-:25])=[O:24])([C:19]([O-:21])=[O:20])[OH:18].[CH3:12][C:11]([CH3:13])=[CH:10][CH2:9][N+:1]1[CH:6]=[CH:5][CH:4]=[C:3]([CH3:7])[CH:2]=1.[CH3:12][C:11]([CH3:13])=[CH:10][CH2:9][N+:1]1[CH:6]=[CH:5][CH:4]=[C:3]([CH3:7])[CH:2]=1.[CH3:12][C:11]([CH3:13])=[CH:10][CH2:9][N+:1]1[CH:6]=[CH:5][CH:4]=[C:3]([CH3:7])[CH:2]=1

Participants

6

Reactant 4

HCID 311Citric AcidHCID 961HydroxideHCID 79703-MethylpyridineHCID 700922-Butene, 1-bromo-3-methyl-

Product 1

HCID 86738219HCID 86738219, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

3-Picoline is reacted with 1-bromo-3-methyl-2-butene in acetonitrile; and the halide intermediate is converted to the hydroxide with Rexyn 201 and then reacted with citric acid to form the citrate.

Sources & evidence

ORD record
ord-cfd70213418f40d29877310bc0becb39
Source dataset
uspto-grants-1982_01
Patent number
US04312367

Reaction notes

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