3-Cyanopyridine → HCID 86738220, compound

HRID 1106205Notes

Reaction equation

HRID 1106205 reaction equation
[C:1]([C:3]1[CH:4]=[N:5][CH:6]=[CH:7][CH:8]=1)#[N:2].Br[CH2:10][CH:11]=[C:12]([CH3:14])[CH3:13].[C:15]([O-:27])(=[O:26])[CH2:16][C:17]([CH2:22][C:23]([O-:25])=[O:24])([C:19]([O-:21])=[O:20])[OH:18].[Na+].[Na+].[Na+]>C(#N)C>[C:15]([O-:27])(=[O:26])[CH2:16][C:17]([CH2:22][C:23]([O-:25])=[O:24])([C:19]([O-:21])=[O:20])[OH:18].[CH3:13][C:12]([CH3:14])=[CH:11][CH2:10][N+:5]1[CH:6]=[CH:7][CH:8]=[C:3]([C:1]#[N:2])[CH:4]=1.[CH3:13][C:12]([CH3:14])=[CH:11][CH2:10][N+:5]1[CH:6]=[CH:7][CH:8]=[C:3]([C:1]#[N:2])[CH:4]=1.[CH3:13][C:12]([CH3:14])=[CH:11][CH2:10][N+:5]1[CH:6]=[CH:7][CH:8]=[C:3]([C:1]#[N:2])[CH:4]=1

Participants

5

Reactant 3

HCID 793-CyanopyridineHCID 6224Trisodium citrateHCID 700922-Butene, 1-bromo-3-methyl-

Product 1

HCID 86738220HCID 86738220, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

3-Cyanopyridine is reacted with 1-bromo-3-methyl-2-butene in acetonitrile; and the halide intermediate is reacted with sodium citrate.

Sources & evidence

ORD record
ord-f22b4ea26c38402d9f55c4e08edec087
Source dataset
uspto-grants-1982_01
Patent number
US04312367

Reaction notes

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