HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1106362Generated: October 30, 2026
Propyltriphenylphosphonium bromide → HCID 10944737, compound
https://huagongshe.com/reaction/1106362
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Propyltriphenylphosphonium bromide | HCID 80374 | — |
| Reactant | 4,4'-Bicyclohexanone | HCID 264825 | — |
| Reactant | Potassium tert-butoxide | HCID 23665647 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 10944737 | HCID 10944737 | — |
Reaction Steps
29.1 g of bicyclohexyl-4,4'-dione and 123 g of propyl-triphenylphosphonium bromide were suspended in 300 ml of THF. The solution was cooled to 0° C., and a solution of 36 g of potassium tert-butoxide in 100 ml of THF was added dropwise, and the mixture was stirred at RT overnight. Conventional work-up gave 4,4'-dipropylidenebicyclohexyl.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06056895 |
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| Source dataset | uspto-grants-2000_05 |
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| ORD ID | ord-9c4c92f60b49411b84dd57fec4538e32 |
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| Source note | uspto-grants-2000_05 |
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