n-Butyl cyclopentadiene → HCID 178506708, 화합물

HRID 1107019노트

반응식

HRID 1107019 반응식
C([Li:5])CCC.[CH2:6]([C:10]1[CH2:14][CH:13]=[CH:12][CH:11]=1)[CH2:7][CH2:8][CH3:9]>CCCCCC.C1COCC1>[CH2:6]([C:10]1([Li:5])[CH:14]=[CH:13][CH:12]=[CH:11]1)[CH2:7][CH2:8][CH3:9]

참가 물질

5

반응물 2

HCID 102598n-Butyl cyclopentadieneHCID 178418339Butyllithium

생성물 1

HCID 178506708HCID 178506708, 화합물

시약·촉매·용매 2

HCID 8028Tetrahydrofuran용매HCID 8058Hexane용매

실험 절차

Being cooled in an ice-water bath, a solution of 50.5 ml of butyl lithium(0.126 mol) in 2.5M hexane were slowly dripped to a solution of 15.4 g(0.126 mol) of butyl-cyclopentadiene(manufactured by RIPP) in 100 ml THF with stirring. After the dripping was finished, the resultant mixture was continuously stirred for 1 hour, a white muddy solution of butyl-cyclopentadienyl lithium was obtained.

후처리

  1. temperatureBeing cooled in an ice-water bath

출처 및 근거

ORD 기록
ord-d06ab5c23a6c42beaeb410da95031605
출처 데이터셋
uspto-grants-2000_05
특허 번호
US06057467

반응 노트

불러오는 중…