HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → HCID 9894114, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 1-Benzylpiperidin-4-ol | HCID 78461 | — |
| Reactant | Diethyl azodicarboxylate | HCID 5462977 | — |
| Reactant | 2-(4-Methoxyphenyl)-3-(4-Hydroxybenzoyl)-6-Methoxybenzo[b]thiophene | HCID 9865197 | — |
| Product | HCID 9894114 | HCID 9894114 | 79% |
Reaction Steps
6-Methoxy-2-(4-methoxyphenyl)-3-(4-hydroxybenzoyl)benzo[b]thiophene (1.17 g, 3.00 mmol), 4-hydroxy-1-benzylpiperidine (1.15 g, 6.00 mmol), triphenylphosphine (1.57 g, 6.00 mmol), and DEAD (6.00 mmol) were converted to product by the procedure of Example 1 to give 1.33 g of the title compound. Yield: 79%. MS(FD) 563(M+). IR (CHCl3) ν max 3030, 3011, 2955, 2846, 1645, 1597, 1476, 1254, 1166.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06060488 |
| Source dataset | uspto-grants-2000_05 |
| ORD ID | ord-7c397810f16e484ca0385c8ec96a8c56 |
| Source note | uspto-grants-2000_05 |