2,2'-(Propane-1,3-diyldiazanediyl)di(ethan-1-ol) → HCID 86755403, compound

HRID 1107610Notes

Reaction equation

HRID 1107610 reaction equation
[OH:1][CH2:2][CH2:3][NH:4][CH2:5][CH2:6][CH2:7][NH:8][CH2:9][CH2:10][OH:11].[C:12](Cl)(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]>>[OH:11][CH2:10][CH2:9][N:8]([C:12](=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH2:7][CH2:6][CH2:5][N:4]([C:12](=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH2:3][CH2:2][OH:1].[OH:11][CH2:10][CH2:9][N:8]([C:12](=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[CH2:7][CH2:6][CH2:5][N:4]([C:12](=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])[CH2:3][CH2:2][OH:1]

Participants

4

Reactant 2

HCID 4152832,2'-(Propane-1,3-diyldiazanediyl)di(ethan-1-ol)HCID 5364783Oleoyl chloride

Product 2

HCID 18787716HCID 18787716, compoundHCID 86755403HCID 86755403, compoundYield 222.5%

Procedure

The procedure described in Example 33 was followed by employing 7.3 g of N,N'-bis(2-hydroxyethyl)-1,3-diaminopropane prepared in Example 33 and 20.9 g of oleoyl chloride, instead of palmitoyl chloride of Example 33, to give 26.7 g of the title compound as viscous oil, which was identified by IR and NMR. The results are shown in Table 3.

Sources & evidence

ORD record
ord-6c3d0cb2da0d46df8ed1500e9433a9e1
Source dataset
uspto-grants-2000_05
Patent number
US06060612

Reaction notes

Loading…