HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,4,6-Trinitroaniline → 1,3-Benzenediamine, 2,4,6-trinitro-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,4,6-Trinitroaniline | HCID 10271 | — |
| Reactant | Dimethylacetamide | HCID 31374 | — |
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Reactant | 2-Propanol, sodium salt (1:1) | HCID 10920443 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Reactant | Sodium t-butoxide | HCID 23676156 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 1,3-Benzenediamine, 2,4,6-trinitro- | HCID 15396 | — |
Reaction Steps
Similarly, when Example 4(a) is repeated except that DMSO is replaced by a volumetrically equivalent amount of DMF or DMAC and sodium methoxide is replaced by a stoichiometrically equivalent amount of sodium ethoxide, sodium n-propoxide, sodium isopropoxide, or sodium tert-butoxide respectively, a mixture of picramide and DATB is produced. The DATB is purified by crystallization from DMF and DMSO.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06069277 |
| Source dataset | uspto-grants-2000_05 |
| ORD ID | ord-4d34375d1c01437497c6271bc8789e27 |
| Source note | uspto-grants-2000_05 |