6639-66-3 → HCID 19021699, compound

HRID 1108989Notes

Reaction equation

HRID 1108989 reaction equation
[CH3:1][O:2][C:3]1[C:11]([O:12][CH2:13][O:14][CH3:15])=[C:10]([O:16][CH3:17])[CH:9]=[C:8]2[C:4]=1[CH2:5][CH2:6][C:7]2=O.CC1C=CC(N=[CH:27][C:28]2[C:29]([NH2:37])=[CH:30][C:31]3[O:35][CH2:34][O:33][C:32]=3[CH:36]=2)=CC=1>>[CH3:17][O:16][C:10]1[C:11]([O:12][CH2:13][O:14][CH3:15])=[C:3]([O:2][CH3:1])[C:4]2[CH2:5][C:6]3[C:7]([C:8]=2[CH:9]=1)=[N:37][C:29]1[CH:30]=[C:31]2[O:35][CH2:34][O:33][C:32]2=[CH:36][C:28]=1[CH:27]=3

Participants

3

Reactant 2

HCID 2416176639-66-3HCID 19021686HCID 19021686, compound

Product 1

HCID 19021699HCID 19021699, compoundYield 79%

Procedure

Using the procedure of Example 1, 4,6-dimethoxy-5-methoxymethoxyindan-1-one (100 mg, 0.4 mmol) is reacted with 6[[(4-methylphenyl)imino]methyl]-1,3-benzodioxol-5-amine (101 mg, 0.4 mmol) to yields 7,9-dimethoxy-8-methoxymethoxy-10H-1,3-dioxolo[4,5-g]indeno[1,2-b]quinoline (120 mg, 79% of theory). This material was used directly in part (B).

Sources & evidence

ORD record
ord-7dc6ed6789ac4aa89d9ba2d7cea6b8db
Source dataset
uspto-grants-1994_06
Patent number
US05318976

Reaction notes

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