HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethyl phosphite → 7,8-dihydro-6,6-dimethyl-7,8-epoxy-6H-pyrano[2,3-f]benz-2,1,3-oxadiazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethyl phosphite | HCID 31215 | — |
| Reactant | 7,8 dihydro-6,6-dimethyl-7,8-epoxy-6H-pyrano[2,3-f]benz-2,1,3-oxadiazole-3-oxide | HCID 11042652 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 7,8-dihydro-6,6-dimethyl-7,8-epoxy-6H-pyrano[2,3-f]benz-2,1,3-oxadiazole | HCID 9837334 | — |
Reaction Steps
1.00 g (4.27 mmol) of 7,8-dihydro-6,6-dimethyl-7,8-epoxy-6H-pyrano[2,3-f]benz-2,1,3-oxadiazole-3-oxide (compound [G]) and 6 ml of benzene were stirred at 60° C., while 0.80 ml (4.70 mmol) of triethyl phosphite was added thereto dropwise within 15 minutes. Next, the obtained mixture was stirred for three hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05319089 |
| Source dataset | uspto-grants-1994_06 |
| ORD ID | ord-6f00b738761747b78f3de0d1fce19ee3 |
| Source note | uspto-grants-1994_06 |