Acetone → 2,3-O-Isopropylidene-D-ribofuranose

HRID 1109257Notes

Reaction equation

HRID 1109257 reaction equation
[O:1]=[CH:2][C@@H:3]([C@@H:5]([C@@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].[CH3:11][C:12]([CH3:14])=O>>[CH3:11][C:12]1([CH3:14])[O:4][C@@H:3]2[C@@H:5]([C@@H:7]([CH2:9][OH:10])[O:8][CH:2]2[OH:1])[O:6]1

Participants

3

Reactant 2

HCID 180AcetoneHCID 5311110Aldehydo-D-ribose

Product 1

HCID 110087122,3-O-Isopropylidene-D-ribofuranose

Procedure

D-ribose 1 of a starting material was reacted with acetone according to the method disclosed in J.Biol.Chem., 102,187-201 (1933) to form a compound 3. Physical data for the compound 3 were found to be in accord with those in literature.

Sources & evidence

ORD record
ord-957272bb3cc54daea2328d177ad79ceb
Source dataset
uspto-grants-1994_06
Patent number
US05319108

Reaction notes

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