HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Alcohol → benzyl chlorooxalate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Alcohol | HCID 244 | — |
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | benzyl chlorooxalate | HCID 11019858 | 94% |
Reaction Steps
Under N2, oxalyl chloride (262 ml) was dissolved in 1 liter anhydrous ether and heated to reflux, at which temperature benzyl alcohol (207 ml) was added over 70 minutes. After refluxing a further 16 hours, ether was stripped and the residue distilled at reduced pressure to yield 372 g (94%) of title product, b.p./0.7 mm 85° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05319103 |
| Source dataset | uspto-grants-1994_06 |
| ORD ID | ord-750184893be74a33a036ee727d7a119a |
| Source note | uspto-grants-1994_06 |