Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Kojic Acid | HCID 3840 | — |
| Reactant | Potassium Iodide | HCID 4875 | — |
| Reactant | 1-Bromooctadecane | HCID 8218 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 14749912 | HCID 14749912 | — |
Reaction Steps
A mixture of 56.8 g (0.4 mole) kojic acid, 55,3 g (0.4 mole) potassium carbonate, 133.3 g (0.4 mole) 1-octadecyl bromide, 1 g potassium iodide and 450 mL anhydrous dimethylformamide is stirred for 10 hours at 90° C.. After cooling, the mixture is mixed with 1.5 L of water, the precipitate formed is filtered off, well stirred up once with ethyl acetate, filtered off and recrystallized from propan-2-ol with the addition of active charcoal. There is obtained a colorless product: m.p. 71°-73° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05322844 |
|---|
| Source dataset | uspto-grants-1994_06 |
|---|
| ORD ID | ord-dfab9c0b7c8d4fec8ae24752c9747e21 |
|---|
| Source note | uspto-grants-1994_06 |
|---|
