HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → HCID 19019891, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Reactant | HCID 19019862 | HCID 19019862 | — |
| Product | HCID 19019891 | HCID 19019891 | — |
Reaction Steps
Reacting 3-(I-hydroxytridecyl)-2-triethylsilylfuran with diphenylphosphoryl azide and diethyl azidocarboxylate gives 3-(1-azidotridecyl)-2-triethylsilylfuran. Reducing this intermediate with lithium aluminum hydride, followed by acetylation with acetic anhydide gives 3-(1-acetamido tridecyl)-2-triethylsilylfuran. Singlet oxygen oxidation of this amide, followed by reduction with sodium borohydride gives 3-(1-acetamidotridecyl)-2(5H)-furanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05322953 |
| Source dataset | uspto-grants-1994_06 |
| ORD ID | ord-9883713f38e84c26b35199829df20e69 |
| Source note | uspto-grants-1994_06 |