HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 15022010, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Methyl Chloride | HCID 6327 | — |
| Reactant | Phenyl Isothiocyanate | HCID 7673 | — |
| Reactant | 1H-2-Benzopyran-1-one, 7-amino-4-chloro-3-ethoxy- | HCID 12324866 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 15022010 | HCID 15022010 | 55% |
Reaction Steps
This compound was prepared by reaction of 7-amino-4-chloro-3-ethoxyisocoumarin with phenyl isothiocyanate at r. t. in THF for 24 hrs. The product was obtained as yellow solid: yield 55%, m.p. 176°-177° C. (dec.); TLC, Rf =0.76 (CH3Cl:MeOH=9:1), MS m/e=374 (M+). Anal. Calcd. for C18H15N2O3ClS: C, 57.62; H, 4.00. Found: C, 57.77; H, 4.04.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05324648 |
| Source dataset | uspto-grants-1994_06 |
| ORD ID | ord-519e0e7cbd1d496a898e656e9989102d |
| Source note | uspto-grants-1994_06 |