HRID1110138

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID753

Glycerol

C3H8O3

$结构：CCCCC/C=C\C/C=C\CCCCCCCC(=O)OC$

HCID5284421

Methyl (9Z,12Z)-octadecadienoate

C19H34O2

2 次

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)OC$

HCID5364509

(Z)-9-Octadecenoic acid methyl ester

C19H36O2

2 次

PRODUCTS

生成物

HCID6354

Ethylene oxide

C2H4O

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)[O-]$

HCID5460221

Oleate

C18H33O2-

$结构：CCCCC/C=C\C/C=C\CCCCCCCC(=O)[O-]$

HCID5460332

(9Z,12Z)-9,12-Octadecadienoic acid ion(1-)

C18H31O2-

PROCEDURE

实验过程

The glyceryl mono/di esters of epoxidized methyl oleate and epoxidized methyl linoleate similarly were prepared following the procedure of Example 1. 0.1 moles of the epoxidized methyl oleate and the epoxidized methyl linoleate each were reacted with 0.2 mol glycerol (100% excess). Analysis of the solid oleate and liquid to semisolid linoleate resulted respectively in an oxirane content of 4.3% and 7.2% and Acid Values of ≤0.6.

WORKUP

后处理

customsimilarly were prepared

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c3a184224a144724b055fd53b8008d18
来源数据集: uspto-grants-1994_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05324846
来源说明: uspto-grants-1994_06

反应 SMILES

[C:1]([O:20]C)(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[C:22]([O:41]C)(=[O:40])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29]/[CH:30]=[CH:31]\[CH2:32]/[CH:33]=[CH:34]\[CH2:35][CH2:36][CH2:37][CH2:38][CH3:39].OC[CH:45]([CH2:47][OH:48])O>>[C:1]([O-:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[C:22]([O-:41])(=[O:40])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29]/[CH:30]=[CH:31]\[CH2:32]/[CH:33]=[CH:34]\[CH2:35][CH2:36][CH2:37][CH2:38][CH3:39].[O:48]1[CH2:47][CH2:45]1