HRID1110154

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCOC(=O)CN(CC(=O)OCC)Cc1cccc(-c2cc(-c3cccc(N)c3)cc(-c3cccc(CN(CC(=O)OCC)CC(=O)OCC)n3)n2)n1

HCID67683131

未命名化合物

PRODUCTS

生成物

结构：Nc1cccc(-c2cc(-c3cccc(CN(CC(=O)O)CC(=O)O)n3)nc(-c3cccc(CN(CC(=O)O)CC(=O)O)n3)c2)c1

HCID54144314

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID21946426

未命名化合物

PROCEDURE

实验过程

The corresponding tetraester, 10c (0.10 g, 0.17 mmol) was dissolved in 5 ml 0.5M KOH-EtOH solution. After 2 hours stirring at room temperature, the ethanol was evaporated to dryness and water was added. The mixture was stirred at room temperature for 30 min whereafter the product was precipitated with 2M hydrochloric acid.

WORKUP

后处理

customthe ethanol was evaporated to dryness and water
additionwas added
stirringThe mixture was stirred at room temperature for 30 min whereafter the product
customwas precipitated with 2M hydrochloric acid

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8bb6878a76a1467398ca1878ebbf5491
来源数据集: uspto-grants-1994_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05324825
来源说明: uspto-grants-1994_06

反应 SMILES

[NH2:1][C:2]1[CH:3]=[C:4]([C:8]2[CH:13]=[C:12]([C:14]3[CH:19]=[CH:18][CH:17]=[C:16]([CH2:20][N:21]([CH2:28][C:29]([O:31]CC)=[O:30])[CH2:22][C:23]([O:25]CC)=[O:24])[N:15]=3)[N:11]=[C:10]([C:34]3[CH:39]=[CH:38][CH:37]=[C:36]([CH2:40][N:41]([CH2:48][C:49]([O:51]CC)=[O:50])[CH2:42][C:43]([O:45]CC)=[O:44])[N:35]=3)[CH:9]=2)[CH:5]=[CH:6][CH:7]=1>[OH-].[K+].CCO>[NH2:1][C:2]1[CH:3]=[C:4]([C:8]2[CH:9]=[C:10]([C:34]3[CH:39]=[CH:38][CH:37]=[C:36]([CH2:40][N:41]([CH2:42][C:43]([OH:45])=[O:44])[CH2:48][C:49]([OH:51])=[O:50])[N:35]=3)[N:11]=[C:12]([C:14]3[CH:19]=[CH:18][CH:17]=[C:16]([CH2:20][N:21]([CH2:22][C:23]([OH:25])=[O:24])[CH2:28][C:29]([OH:31])=[O:30])[N:15]=3)[CH:13]=2)[CH:5]=[CH:6][CH:7]=1