Benzoyl chloride, 3-nitro- → HCID 4427136, compound

HRID 1110239Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][CH:12]=1)[C:7](Cl)=[O:8])([O-:3])=[O:2].[CH2:13]([NH2:23])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22]>>[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][CH:12]=1)[C:7]([NH:23][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])=[O:8])([O-:3])=[O:2]

Participants

Reactant 2

HCID 8495Benzoyl chloride, 3-nitro-

HCID 8916Decylamine

Product 1

HCID 4427136HCID 4427136, compound

Procedure

Using this procedure 3-nitrobenzoyl chloride was treated with decylamine to give 3-nitro-N-decylbenzamide, mp 86°-88°, which was hydrogenated to give 3-amino-N-decylbenzamide, mp 56°-58°, which gave nmr and mass spectra consistent with the structure.

Sources & evidence

ORD record: ord-605c1094f27547a5bac1e838fc2dce0a
Source dataset: uspto-grants-1994_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05324747

Reaction notes

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