Ethanol → HCID 86744379, compound

Participants

Reaction Steps

The same autoclave as in Example 10 was charged with 1 g (10.7 m moles) of aniline, 8 g (173.6 m moles) of ethanol, 8 g (66.6 m moles) of sulfolane and 0.48 g (2.52 m moles) of copper iodide. Carbon monoxide and air were put in the autoclave under pressure to adjust their partial pressures to 75 kg/cm2G and 35 kg/cm2G, respectively, and the reaction was carried out at a temperature of 158° C. for 2 hours. Consequently, the urethane (ethyl N-phenylcarbamate) yield based on aniline was 95.8% and the amount of diethyl carbonate obtained was 0.52 m moles.

Provenance & Evidence