1-Bromo-4-nitrobenzene → HCID 23325107, compound

HRID 1110659Notes

Reaction equation

HRID 1110659 reaction equation
Cl[C:2]1[CH:21]=[CH:20][C:5]([O:6][C:7]2[CH:19]=[CH:18][C:10]([O:11][CH:12]([CH2:16]C)[C:13]([Cl:15])=[O:14])=[CH:9][CH:8]=2)=[CH:4][CH:3]=1.ClC1C=CC(OC2C=CC(OC(CCC)C(Cl)=O)=CC=2)=CC=1.BrC1C=CC([N+:51]([O-:53])=[O:52])=CC=1>>[N+:51]([C:2]1[CH:21]=[CH:20][C:5]([O:6][C:7]2[CH:19]=[CH:18][C:10]([O:11][CH:12]([CH3:16])[C:13]([Cl:15])=[O:14])=[CH:9][CH:8]=2)=[CH:4][CH:3]=1)([O-:53])=[O:52]

Participants

4

Reactant 3

HCID 114661-Bromo-4-nitrobenzeneHCID 54175059HCID 54175059, compoundHCID 54554340HCID 54554340, compound

Product 1

HCID 23325107HCID 23325107, compound

Procedure

2-bromoacetic acid, (b) 2-bromobutyric acid, and (c) 2-bromovaleric acid in the above (A), were used to obtain (a'), 4-(4-chlorophenoxy)phenoxyacetic acid chloride, (b') 2-(4-(4-chlorophenoxy)phenoxybutyric acid chloride, (c') 2-(4-(4-chlorophenoxy)phenoxy)valeric acid chloride, respectively. Also, by using (d) 4-bromonitrobenzene instead of 4-bromochlorobenzene in the above (a), (d') 2-(4-(4-nitrophenoxy)phenoxy)propionic acid chloride was obtained.

Sources & evidence

ORD record
ord-1e681495371343ba9493af8aabba9d02
Source dataset
uspto-grants-1990_12
Patent number
US04976773

Reaction notes

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