3-Nitrobenzonitrile → 3-Aminobenzylamine

HRID 1111252Notes

Reaction equation

HRID 1111252 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[C:7]#[N:8])([O-])=O>[Ni]>[NH2:1][C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[CH2:7][NH2:8]

Participants

3

Reactant 1

HCID 120793-Nitrobenzonitrile

Product 1

HCID 46288313-AminobenzylamineYield 49%

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

A process wherein M-nitrobenzonitrile is subjected to high pressure catalytic reduction with Raney nickel catalyst to obtain m-aminobenzylamine (yield: 49%) (J.R. Griffith et al., NRL Report 6439)).

Sources & evidence

ORD record
ord-eb4d0254f8e14f03877f3f0d83f6c83c
Source dataset
uspto-grants-1990_12
Patent number
US04978792

Reaction notes

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