1,5-Hexadiene → HCID 22152516, compound

Participants

Reaction Conditions

Reaction Steps

After 410 g (5 mol) of 1,5-hexadiene and 0.035 g of chloroplatinic acid had been placed into a 1 L three-necked flask equipped with an agitation mechanism, the contents were agitated. Then, 134 g (1 mol) of tetramethyldisiloxane were added dropwise into the resulting mixture for approximately 1.5 h while the temperature was being gradually raised to 80° C. Then, the contents were reacted at 80° C. for an additional 2 h. After unreacted components had been distilled and removed from the resulting mixture at 80° C. and 3 mm Hg, 178 g of di(5-hexenyl)tetramethyldisiloxane were obtained. 1H-NMR and 13C-NMR analyses revealed that the objective product had been synthesized.

Provenance & Evidence