Dibutylamine → HCID 20263407, compound

HRID 1111573Notes

Reaction equation

HRID 1111573 reaction equation
[C:1]([Cl:4])(Cl)=[S:2].[CH2:5]([NH:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH2:6][CH2:7][CH3:8]>C(OCC)C>[CH2:5]([N:9]([CH2:10][CH2:11][CH2:12][CH3:13])[C:1]([Cl:4])=[S:2])[CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 8148DibutylamineHCID 10040Thiophosgene

Product 1

HCID 20263407HCID 20263407, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent2×

Procedure

To a solution of 29.9g (0.26 mole) thiophosgene in 600 ml ethyl ether at 0° was added a solution of 25.8g (0.20 mole) dibutylamine 20.2g (0.20 mole) triethylamine and 250 ml ethyl ether over a period of 35 minutes during which time solids formed. After stirring an additional one hour, the mixture was filtered and the resulting filtrate was removed of volatiles under reduced pressures to yield 35g of crude dibutylthiocarbamoyl chloride.

Workup

  1. customformed
  2. filtrationthe mixture was filtered
  3. customthe resulting filtrate was removed of volatiles under reduced pressures

Sources & evidence

ORD record
ord-2471c4ce3b394dcd9f0e70b46c0a0e30
Source dataset
uspto-grants-1978_10
Patent number
US04118378

Reaction notes

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