HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → 2-(4-Methylphenyl)-1,3-dithiolanium fluoroborate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | 2-(4'-Methylphenyl)-1,3-dithiolane | HCID 31708 | — |
| Reactant | Triphenylcarbenium tetrafluoroborate | HCID 2723955 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 2-(4-Methylphenyl)-1,3-dithiolanium fluoroborate | HCID 22765715 | 14% |
Reaction Steps
A 3.30 g (0.01 mole) sample of triphenylcarbenium tetrafluoroborate is added to a solution 3.92 g of 2-(4-methylphenyl)-1,3-dithiolane in 35 ml of acetonitrile under nitrogen at 5° C. Methylene chloride is added then ether. The yellow solid is collected and washed with ether. There is obtained 0.7 g (14% yield) of 2-(4-methylphenyl)-1,3-dithiolanium fluoroborate, m.p. 119°-120° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04119639 |
| Source dataset | uspto-grants-1978_10 |
| ORD ID | ord-1712c9c33a704172913adce2f5473f95 |
| Source note | uspto-grants-1978_10 |