1,3-Propanediamine → N,N'-(1,3-propylene)-bis[2-hydroxynonylamine]

HRID 1111914Notes

Reaction equation

HRID 1111914 reaction equation
[CH2:1]1[O:10][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[CH2:11]([NH2:15])[CH2:12][CH2:13][NH2:14]>CO>[CH2:11]([NH:15][CH2:1][CH:2]([OH:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:12][CH2:13][NH:14][CH2:1][CH:2]([OH:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Participants

4

Reactant 2

HCID 4281,3-PropanediamineHCID 5511812-Heptyloxirane

Product 1

HCID 21332359N,N'-(1,3-propylene)-bis[2-hydroxynonylamine]

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

In a manner similar to that of Example 1, condensation of 1-nonene oxide (120 g.) and 1,3-propanediamine (31.2 g.) and two recrystallizations of the resulting product from methanol gave N,N'-(1,3-propylene)-bis[2-hydroxynonylamine] (I: R = CH3 (CH2)6, R' = H, X = (CH2)3, Z = H) (13.2 g., m.p. 107.0°-109.0° C.).

Sources & evidence

ORD record
ord-ac7778fa14d94a0d97811f2ab47d24b0
Source dataset
uspto-grants-1978_10
Patent number
US04119668

Reaction notes

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