HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1112231Generated: November 1, 2026
Diethylether water → 3,4,7-Trimethylnona-2,6-dien-1-ol
https://huagongshe.com/reaction/1112231
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Diethylether water | HCID 21584184 | — |
| Reactant | Sodium bis(2-methoxyethoxy)aluminiumhydride | HCID 21584525 | — |
| Reactant | HCID 53646416 | HCID 53646416 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 3,4,7-Trimethylnona-2,6-dien-1-ol | HCID 54063538 | — |
Reaction Steps
157 g. of ethyl 3,4,7-trimethyl-2,6-nonadienecarboxylate are dissolved in 300 ml. of benzene and added dropwise while cooling with ice to a solution of 370 g. of 70% sodium bis-(methoxyethoxy)-aluminum hydride in benzene. The mixture is then stirred at 40° C. for 2 hours and subsequently worked up with water/ether as described earlier. The 3,4,7-trimethyl-2,6-nonadien-1-ol obtained boils at 79°-84° C./0.09 mmHg.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04120974 |
|---|
| Source dataset | uspto-grants-1978_10 |
|---|
| ORD ID | ord-09e45984bda641b586bf46b9cd554a6e |
|---|
| Source note | uspto-grants-1978_10 |
|---|
