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HRID11123

反应详情

EQUATION

反应方程式

HRID 11123 的结构方程式

REACTANTS

反应物

1
结构：COc1cc2c3c([nH]c2cc1OCc1ccccc1)CC(c1ccccc1Cl)C1C(=O)NC(=O)C31
HCID86760213

未命名化合物

PRODUCTS

生成物

1
结构：COc1cc2c(cc1OCc1ccccc1)[nH]c1cc(-c3ccccc3Cl)c3c(c12)C(=O)NC3=O
HCID86760215

未命名化合物

收率 93%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Mn+4].[O-2].[O-2]
催化剂HCID178418406

未命名化合物

PROCEDURE

实验过程

Aromatisation of (161) prepared as described in example 261 with manganese dioxide using the procedure described in example 79 gave the carbazole (162) (93%) as an orange powder, mp 260–264° C. 1H NMR δ [(CD3)2SO] 11.86 (s, 1H), 11.01 (s, 1H), 8.43 (s, 1H), 7.58–7.34 (m, 10H), 7.26 (s, 1H), 5.26 (s, 2H), 3.91 (s, 3H). Found: C, 69.65; H, 3.84; N, 5.61. C28H19ClN2O4 requires C, 69.64; H, 3.97; N, 5.80.