4-Chloro-2,6-lutidine-1-oxide hydrochloride → 4-Chloro-2,6-dimethylpyridine 1-oxide

HRID 1112462Notes

Reaction equation

HRID 1112462 reaction equation
NC1C=C([N+]([O-])=O)C=C(C)[N+]=1[O-].Cl.[Cl:14][C:15]1[CH:16]=[C:17]([CH3:23])[N+:18]([O-:22])=[C:19]([CH3:21])[CH:20]=1>>[Cl:14][C:15]1[CH:16]=[C:17]([CH3:23])[N+:18]([O-:22])=[C:19]([CH3:21])[CH:20]=1

Participants

3

Reactant 2

HCID 227642674-Chloro-2,6-lutidine-1-oxide hydrochlorideHCID 178428768HCID 178428768, compound

Product 1

HCID 5878434-Chloro-2,6-dimethylpyridine 1-oxide

Procedure

Following the procedure of Example 1, Part B, but substituting 4-nitro-2,6-lutidine-1-oxide [as prepared by Ochiai, J. Org. Chem. 18, p. 534 (1953)] for 6-amino4-nitro-2-picoline-1-oxide, there was prepared 4-chloro-2,6-lutidine-1-oxide hydrochloride.

Sources & evidence

ORD record
ord-1bb67b11b9c846ebb87c57abef66dff5
Source dataset
uspto-grants-1978_10
Patent number
US04122264

Reaction notes

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