Methanol → 3-(2-Methoxyphenoxy)-5-(pyridin-3-yloxy)-benzene-1,2-diamine

HRID 1115439Notes

Reaction equation

HRID 1115439 reaction equation
[C+4:29].[CH3:1][O:2][c:3]1[c:4]([O:5][c:6]2[c:7]([N+:20]([O-:21])=[O:22])[c:8]([NH2:9])[cH:10][c:11]([O:13][c:14]3[cH:15][n:16][cH:17][cH:18][cH:19]3)[cH:12]2)[cH:23][cH:24][cH:25][cH:26]1.[CH3:37][OH:38].[H:27][H:28].[OH-:30].[OH-:32].[OH-:33].[OH-:34].[OH-:35].[OH-:36].[Pd+2:31]>>[CH3:1][O:2][c:3]1[c:4]([O:5][c:6]2[c:7]([NH2:20])[c:8]([NH2:9])[cH:10][c:11]([O:13][c:14]3[cH:15][n:16][cH:17][cH:18][cH:19]3)[cH:12]2)[cH:23][cH:24][cH:25][cH:26]1

Participants

7

Reactant 6

HCID 887MethanolHCID 961Hydroxide6×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 231451253-(2-Methoxyphenoxy)-2-nitro-5-(pyridin-3-yloxy)-anilineHCID 178418361HCID 178418361, compoundHCID 178420935HCID 178420935, compound

Product 1

HCID 231457673-(2-Methoxyphenoxy)-5-(pyridin-3-yloxy)-benzene-1,2-diamine

Sources & evidence

ORD record
ord-d1d3ce43b5f44b2ca2c91608d7b7cebc
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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