Potassium Cation → 6-(3-Ethynyl-phenyl)-4,4-dimethyl-1,4-dihydro-benzo[d][1,3]oxazin-2-one

HRID 1121221Notes

Reaction equation

HRID 1121221 reaction equation
[C:26](=[O:27])([O-:28])[O-:29].[CH3:1][C:2]1([CH3:25])[c:3]2[c:4]([cH:9][cH:10][c:11](-[c:13]3[cH:14][c:15]([C:19]#[C:20][Si:21]([CH3:22])([CH3:23])[CH3:24])[cH:16][cH:17][cH:18]3)[cH:12]2)[NH:5][C:6](=[O:8])[O:7]1.[CH3:32][OH:33].[K+:30].[K+:31]>>[CH3:1][C:2]1([CH3:25])[c:3]2[c:4]([cH:9][cH:10][c:11](-[c:13]3[cH:14][c:15]([C:19]#[CH:20])[cH:16][cH:17][cH:18]3)[cH:12]2)[NH:5][C:6](=[O:8])[O:7]1

Participants

5

Reactant 4

HCID 813Potassium Cation2×HCID 887MethanolHCID 19660Carbonate IonHCID 99029764,4-Dimethyl-6-(3-trimethylsilanylethynyl-phenyl)-1,4-dihydro-benzo[d][1,3]oxazin-2-one

Product 1

HCID 98141916-(3-Ethynyl-phenyl)-4,4-dimethyl-1,4-dihydro-benzo[d][1,3]oxazin-2-one

Sources & evidence

ORD record
ord-b2c7068108334b08928696c1403614f9
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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