Acetic Acid → ethyl 5-acetyl-8-amino-1-(1,3-benzodioxol-5-yl)-4,5-dihydro-1H-pyrazolo[4,3-c]quinoline-3-carboxylate

HRID 1123822Notes

Reaction equation

HRID 1123822 reaction equation
[C:1]([CH3:2])(=[O:3])[N:4]1[CH2:5][c:6]2[c:7]([n:17](-[c:25]3[cH:26][c:27]4[c:28]([cH:32][cH:33]3)[O:29][CH2:30][O:31]4)[n:18][c:19]2[C:20](=[O:21])[O:22][CH2:23][CH3:24])-[c:8]2[cH:9][c:10]([N+:14]([O-:15])=[O:16])[cH:11][cH:12][c:13]21.[CH3:34][C:35](=[O:36])[OH:37].[OH-:38].[OH-:39].[Pd+2:40]>>[C:1]([CH3:2])(=[O:3])[N:4]1[CH2:5][c:6]2[c:7]([n:17](-[c:25]3[cH:26][c:27]4[c:28]([cH:32][cH:33]3)[O:29][CH2:30][O:31]4)[n:18][c:19]2[C:20](=[O:21])[O:22][CH2:23][CH3:24])-[c:8]2[cH:9][c:10]([NH2:14])[cH:11][cH:12][c:13]21

Participants

5

Reactant 4

HCID 176Acetic AcidHCID 961Hydroxide2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 21092643ethyl 5-acetyl-1-(1,3-benzodioxol-5-yl)-8-nitro-4,5-dihydro-1H-pyrazolo[4,3-c]quinoline-3-carboxylate

Product 1

HCID 21092645ethyl 5-acetyl-8-amino-1-(1,3-benzodioxol-5-yl)-4,5-dihydro-1H-pyrazolo[4,3-c]quinoline-3-carboxylate

Sources & evidence

ORD record
ord-1bf719ad524449b186216a5e8cd407ca
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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