Potassium Cation → 8-Cyclopropyl-6-ethynyl-2,2,4,4-tetramethylchroman

HRID 1125374Notes

Reaction equation

HRID 1125374 reaction equation
[C:24](=[O:25])([O-:26])[O-:27].[CH3:30][OH:31].[CH:1]1([c:4]2[cH:5][c:6]([C:18]#[C:19][Si:20]([CH3:21])([CH3:22])[CH3:23])[cH:7][c:8]3[c:13]2[O:12][C:11]([CH3:14])([CH3:15])[CH2:10][C:9]3([CH3:16])[CH3:17])[CH2:2][CH2:3]1.[K+:28].[K+:29]>>[CH:1]1([c:4]2[cH:5][c:6]([C:18]#[CH:19])[cH:7][c:8]3[c:13]2[O:12][C:11]([CH3:14])([CH3:15])[CH2:10][C:9]3([CH3:16])[CH3:17])[CH2:2][CH2:3]1

Participants

5

Reactant 4

HCID 813Potassium Cation2×HCID 887MethanolHCID 19660Carbonate IonHCID 187197898-Cyclopropyl-6-trimethylsilanylethynyl-2,2,4,4-tetramethyl chroman

Product 1

HCID 225690068-Cyclopropyl-6-ethynyl-2,2,4,4-tetramethylchroman

Sources & evidence

ORD record
ord-726143aa582543148f91258b43287365
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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