HRID1134

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID12527

1-Iodohexane

C6H13I

结构：COC(=O)c1ccc(-c2ccc3cc(O)c(C45CC6CC(CC(C6)C4)C5)cc3c2)cc1O

HCID22000320

未命名化合物

PRODUCTS

生成物

结构：CCCCCCOc1cc2ccc(-c3ccc(C(=O)OC)c(O)c3)cc2cc1C12CC3CC(CC(C3)C1)C2

HCID22000297

未命名化合物

收率 55%

PROCEDURE

实验过程

Following the basic procedure of Example 11, by reacting 430 mg (1 mmol) of methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hydroxy-2-naphthyl]benzoate with 180 μl (1.2 mmol) of 6-iodohexane, 280 mg (55%) of methyl 2-hydroxy-4-[7-(1-adamantyl)-6-hexyloxy-2-naphthyl]benzoate were obtained.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-dbade7089fdb4aeda06e0dbd6d0e1ec8
来源数据集: uspto-grants-1998_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05723499
来源说明: uspto-grants-1998_03

反应 SMILES

[OH:1][C:2]1[CH:11]=[C:10]([C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][C:16]([C:23]45[CH2:32][CH:27]6[CH2:28][CH:29]([CH2:31][CH:25]([CH2:26]6)[CH2:24]4)[CH2:30]5)=[C:17]([OH:22])[CH:18]=3)[CH:13]=2)[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5].I[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]>>[OH:1][C:2]1[CH:11]=[C:10]([C:12]2[CH:21]=[CH:20][C:19]3[C:14](=[CH:15][C:16]([C:23]45[CH2:24][CH:25]6[CH2:26][CH:27]([CH2:28][CH:29]([CH2:31]6)[CH2:30]4)[CH2:32]5)=[C:17]([O:22][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[CH:18]=3)[CH:13]=2)[CH:9]=[CH:8][C:3]=1[C:4]([O:6][CH3:7])=[O:5]