N-bromobutanimide → N-(Dodecylsulfonyl)-2-(bromonitromethylene)-tetrahydro-2H-1,3-thiazine

HRID 1153720Notes

Reaction equation

HRID 1153720 reaction equation
[CH2:1]([S:13]([N:16]1[CH2:21][CH2:20][CH2:19][S:18][C:17]1=[CH:22][N+:23]([O-:25])=[O:24])(=[O:15])=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Br:26]N1C(=O)CCC1=O>>[CH2:1]([S:13]([N:16]1[CH2:21][CH2:20][CH2:19][S:18][C:17]1=[C:22]([Br:26])[N+:23]([O-:25])=[O:24])(=[O:14])=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

3

Reactant 2

HCID 67184N-bromobutanimideHCID 539120323-(Dodecane-1-sulfonyl)-2-(nitromethylidene)-1,3-thiazinane

Product 1

HCID 54005755N-(Dodecylsulfonyl)-2-(bromonitromethylene)-tetrahydro-2H-1,3-thiazine

Procedure

was prepared, as a yellow solid, m.p.: 70°-71° C., by treating (3A) with N-bromosuccinimide, according to the procedure described in Example 1.

Workup

  1. customwas prepared, as a yellow solid, m.p.: 70°-71° C.

Sources & evidence

ORD record
ord-5e28bf01d8684774a8bf2821fe5f9019
Source dataset
uspto-grants-1984_12
Patent number
US04486427

Reaction notes

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