Sodium Dithionite → HCID 20436416, compound

HRID 1153772Notes

Reaction equation

[NH2:1][C:2]1[N+:7]([O-])=[C:6]2[CH2:9][N:10]([C:13](=[O:15])[CH3:14])[CH2:11][CH2:12][C:5]2=[N:4][CH:3]=1.S(S([O-])=O)([O-])=O.[Na+].[Na+]>>[NH2:1][C:2]1[N:7]=[C:6]2[CH2:9][N:10]([C:13](=[O:15])[CH3:14])[CH2:11][CH2:12][C:5]2=[N:4][CH:3]=1

Participants

Reactant 2

HCID 24489Sodium Dithionite

HCID 178473764HCID 178473764, compound

Product 1

HCID 20436416HCID 20436416, compound

Procedure

This intermediate was prepared analogous to Example 19 from 3-amino-6-acetyl-5,6,7,8-tetrahydro-pyrido[3,4-b]pyrazine-4-oxide by reduction with sodium dithionite.

Sources & evidence

ORD record: ord-f4eff46bbd8d4ed4afa3bdb99c6bffb9
Source dataset: uspto-grants-1984_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04486433

Reaction notes

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