Bis(alpha-methoxy-p-tolyl) ether → Ethenol;ethenoxymethoxyethene;ethenyl acetate

HRID 1153840Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1153840
C1(NC2C=CC([N+]#N)=[C:10]([O:16]C)[CH:9]=2)C=CC=CC=1.C[O:19][CH2:20][C:21]1C=C[C:24]([O:27][C:28]2[CH:33]=C[C:31]([CH2:34][O:35][CH3:36])=CC=2)=[CH:23]C=1.C1(C)C=C(C)C=C(C)C=1S([O-])(=O)=O>COCCO>[CH3:23][C:24]([O:27][CH:28]=[CH2:33])=[O:16].[CH2:21]=[CH:20][OH:19].[CH2:9]=[CH:10][O:16][CH2:36][O:35][CH:34]=[CH2:31]

Komponenten

5

Edukt 3

HCID 75635Bis(alpha-methoxy-p-tolyl) etherHCID 83541Benzenediazonium, 2-methoxy-4-(phenylamino)-HCID 38762462,4,6-Trimethylbenzene-1-sulfonate

Produkt 1

HCID 173927Ethenol;ethenoxymethoxyethene;ethenyl acetate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 80192-MethoxyethanolLösungsmittel2×

Versuchsvorschrift

To 100 grams of 2-methoxyethanol, available from Union Carbide Corporation as "methyl cellosolve", were added the following components: 1.35 grams of a polyvinyl-formal resin commercially available from Monsanto Corporation as "Formvar 12/85", 0.20 g of a polymeric condensation product of 4-(phenylamino)-2-methoxybenzene diazonium salt and bis-(4-methoxymethylphenyl) ether, isolated in the form of a mesitylene sulfonate, as described in U.S. Pat. No. 3,849,393, assigned to Kalle AG, 0.01 g of 4-phenylazodiphenylamine and 0.02 g of H3PO4. After stirring at room temperature the solution was filtered through coarse filter paper.

Quellen und Nachweise

ORD-Eintrag
ord-2a62a08e035749da91c7612237a25b0d
Quelldatensatz
uspto-grants-1984_12
Patentnummer
US04486529

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