1,1-Bis(methylthio)-2-nitroethylene → HCID 70506038, compound

Participants

Reaction Steps

A mixture of 3-(6-dimethylaminomethyl-2-pyridylthio)-propylamine (1.13 g, 0.005 mol) and 1,1-bis(methylthio)-2-nitroethene (0.86 g, 0.0052 mol) in acetonitrile (10 ml) is warmed briefly to effect solution and then allowed to stand at ambient temperature for 18 hours. The solvent is evaporated and the residue is chromotographed on silica gel (50 g) eluting with 3-7% methanol/chloroform to give 1.25 g of a glassy product.

Provenance & Evidence