3-Phenoxy-alpha-ethynylbenzylalcohol → 1-(3-Phenoxyphenyl)prop-2-en-1-ol

HRID 1155373Notes

Reaction equation

HRID 1155373 reaction equation
[H][H].[O:3]([C:10]1[CH:11]=[C:12]([CH:17]=[CH:18][CH:19]=1)[CH:13]([OH:16])[C:14]#[CH:15])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1>O1CCOCC1>[O:3]([C:10]1[CH:11]=[C:12]([CH:17]=[CH:18][CH:19]=1)[CH:13]([OH:16])[CH:14]=[CH2:15])[C:4]1[CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=1

Participants

4

Reactant 2

HCID 129190923-Phenoxy-alpha-ethynylbenzylalcoholHCID 178418361HCID 178418361, compound

Product 1

HCID 129613931-(3-Phenoxyphenyl)prop-2-en-1-ol

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

With stirring, at room temperature and under normal pressure, hydrogen was introduced (3.37 l H2 ; 0° C./760 mm Hg) in a solution of 33.7 3-phenoxy-α-ethynylbenzylalcohol in 340 ml dioxan and 1.7 g Lindlar catalysator.

Sources & evidence

ORD record
ord-30df5967b93d43c5aeae8935bc2bf5ea
Source dataset
uspto-grants-1981_11
Patent number
US04301304

Reaction notes

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