HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,4-Dinitrobenzenesulfenyl chloride → HCID 20561020, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,4-Dinitrobenzenesulfenyl chloride | HCID 68251 | — |
| Reactant | 2,3-Bis(4-methoxyphenyl)thiophene | HCID 11403717 | — |
| Solvent | Trifluoroacetic acid | HCID 6422 | — |
| Product | HCID 20561020 | HCID 20561020 | 85.2% |
Reaction Steps
A suspension of 2,3-bis(4-methoxyphenyl)thiophene (6.6 g, 22.3 mmoles) and 2,4-dinitrobenzenesulfenyl chloride (5.5 g, 22.3 mmoles) in 55 ml of trifluoroacetic acid was heated at reflux for 15 minutes. The reaction mixture was cooled in ice; the lustrous crystals were collected and washed with cold ether to give the title compound (9.4 g), m.p. 143°-145°
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04302461 |
| Source dataset | uspto-grants-1981_11 |
| ORD ID | ord-e47269fde309406fb54ae29774fdf931 |
| Source note | uspto-grants-1981_11 |